manifestation_id original_title title_alternative title_transcription statement_of_responsibility serial manifestation_identifier creator contributor publisher date_of_publication year_of_publication publication_place manifestation_created_at manifestation_updated_at carrier_type content_type frequency language isbn issn ncid volume_number volume_number_string edition edition_string issue_number issue_number_string serial_number extent start_page end_page dimensions height width depth manifestation_price access_address manifestation_required_role abstract description identifier:unknown identifier:nbn identifier:isbn10 identifier:iss_itemno identifier:online_isbn identifier:print_isbn identifier:print_issn identifier:online_issn identifier:escidoc identifier:nims series_statement_id series_statement_original_title series_statement_title_subseries series_statement_title_subseries_transcription series_statement_title_transcription series_statement_creator series_statement_volume_number series_statement_series_master series_statement_root_manifestation_id series_statement_manifestation_id series_statement_position series_statement_note series_statement_created_at series_statement_updated_at subject:ndlsh subject:unknown subject:bsh classification:ndc8 classification:ndc9 classification:udc doi jpno ncid lccn iss_itemno item_id item_identifier binding_item_identifier call_number library shelf item_note accepted_at acquired_at item_created_at item_updated_at 103288 Structure refinement of quaternary RE-B-C-Si compounds: Y3−x(B12)3(CSi)Si8 (x ≈ 0.96) and Dy3−x(B12)3(CSi)Si8 (x ≈ 0.90) "" "" "" 2009-07-24 00:00:00 +0900 2009 2015-05-28 18:03:03 +0900 2023-07-31 14:19:51 +0900 online_resource text unknown unknown "" "" 12015 https://hdl.handle.net/20.500.11932/458239 Guest We refined the crystal structure of quaternary RE-B-C-Si (RE = Y or Dy) compounds Y3-x(B12)3(CSi)Si8 (x ≈ 0.96) and Dy3-x(B12)3(CSi)Si8 (x ≈ 0.90). Both compounds have a trigonal crystal structure with space group Rm (No. 166). They have previously been assigned as ternary RE-B-Si compounds, but we incorporated carbon to the new structure refinements. The refinement for Y3-x(B12)3(CSi)Si8 achieved a final R1 = 0.0288 for 1178 independent reflections with F0 > 4σ(F0) and 0.0431 for all 1484 reflections, and the refinement for Dy3-x(B12)3(CSi)Si8 achieved a final R1= 0.0382 for 2009 independent reflections with F0 > 4σ(F0) and 0.0385 for all 2022 reflections. The new structure refinements suggest the presence of (B12)3-Si-C-(B12)3 units, which, together with two other units, B12 icosahedron cluster and Si8 ethane like cluster, stabilize the RE3-x(B12)3(CSi)Si8 crystal structure. "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" "" quaternary RE-B-C-Si compounds//Y3−x(B12)3(CSi)Si8 (x ≈ 0.96)//Dy3−x(B12)3(CSi)Si8 (x ≈ 0.90)//structure refinement//quaternary RE-B-C-Si compounds//Y3−x(B12)3(CSi)Si8 (x ≈ 0.96)//Dy3−x(B12)3(CSi)Si8 (x ≈ 0.90)//structure refinement//quaternary RE-B-C-Si compounds//Y3−x(B12)3(CSi)Si8 (x ≈ 0.96)//Dy3−x(B12)3(CSi)Si8 (x ≈ 0.90)//structure refinement "" "" "" "" 95825 web web 2023-07-31 14:19:51 +0900 2023-07-31 14:19:51 +0900