資料の表示

次へ 前へ 一覧に戻る : 詳細検索

[M] A Novel Boron-Rich Scandium Borocarbide; Sc4.5−xB57−y+zC3.5−z(x=0.27, y=1.1, z=0.2) オンラインリソース

著者: (出版日: 2002-11-21)

コレクション: NIMS成果物
形態: オンラインリソース オンラインリソース
言語: 不明
ページ数と大きさ:
件名:
分類:
識別子:
全文ファイル
アブストラクト:

A novel ternary boron-rich scandium borocarbide Sc4.5−xB57−y+zC3.5−z (x=0.27, y=1.1, z=0.2) was found. Single crystals were obtained by the floating zone method by adding a small amount of Si. Single-crystal structure analysis revealed that the compound has an orthorhombic structure with lattice constants of a=1.73040(6), b=1.60738(6) and c=1.44829(6) nm and space group Pbam (No. 55). The crystal composition ScB13.3C0.78Si0.008 calculated from the structure analysis agreed with the measured composition of ScB12.9C0.72Si0.004. The orthorhombic crystal structure is a new structure type of boron-rich borides and there are six structurally independent B12 icosahedra I1—I6, one B8/B9 polyhedron and nine bridging sites all which interconnect each other to form a three-dimensional boron framework. The main structural feature of the boron framework structure can be understood as a layer structure where two kinds of boron icosahedron network layer L1 and L2 stack each other along the c-axis. There are seven structurally independent Sc sites in the open spaces between the boron icosahedron network layers.