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[M] Vanadium doping in YB44Si1.0 Online resource


(Date of publication: 2010-06-14)
https://hdl.handle.net/20.500.11932/457941 Web

Collection: NIMS成果物
Form: Online resource Online resource
Language: unknown
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Identifier: Handle URI: https://hdl.handle.net/20.500.11932/457941
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Abstract:

Vanadium doping in yttrium boron-rich boride; YB44Si1.0, is investigated. Vanadium atoms occupy two sites. First, newly discovered site with site occupancy of approximately 3% is far from yttrium atoms and is coordinated "tetrahedrally" by three boron icosahedra and one B12Si3 polyhedron. Another is Si/V mixed-occupation site with site occupancy of ~ 63/6.2 %; it is close to yttrium atoms and is tetrahedrally coordinated by four boron icosahedra. Chemical formula determined from the structure analysis is Y0.96V0.062B41.2Si0.93. Magnetic susceptibility of V-doped YB44Si1.0 was measured from 2 K to 300 K. The vanadium doping in YB44Si1.0 did not result in superconductivity.

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